Reactivity Enhancement of a Zerovalent Diboron Compound by Desymmetrization.
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DOI: 10.1021/jacs.8b06930
Abstract: The desymmetrization of the cyclic (alkyl)(amino)carbene-supported diboracumulene B2(cAACMe)2 (cAACMe = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) by monoadduct formation with IMeMe (1,3-dimethylimidazol-2-ylidene) yields the zerovalent sp-sp2 diboron compound B2(cAACMe)2(IMeMe), which provides a versatile platform for the synthesis of novel symmetrical… read more here.
Keywords: imeme; diboron; diboron compound; zerovalent ... See more keywords