Catalytic Alkene Difunctionalization via Imidate Radicals.
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DOI: 10.1021/jacs.8b07578
Abstract: The first catalytic strategy to harness imidate radicals has been developed. This approach enables alkene difunctionalization of allyl alcohols by photocatalytic reduction of their oxime imidates. The ensuing imidate radicals undergo consecutive intra- and intermolecular… read more here.
Keywords: catalytic alkene; imidate; imidate radicals; difunctionalization via ... See more keywords