Highly Boosting Circularly Polarized Luminescence of Chiral Metal-Imidazolate Frameworks.
Sign Up to like & getrecommendations! Published in 2023 at "Advanced science"
DOI: 10.1002/advs.202207333
Abstract: To develop a simple and general method for improving the circularly polarized luminescence (CPL) performances of materials is of great significance. In this work, two pairs of CPL-active homochiral metal-organic frameworks (MOFs) P/M-Et and P/M-Et(Cd)… read more here.
Keywords: imidazolate; highly boosting; luminescence; polarized luminescence ... See more keywords
Meltable Mixed-Linker Zeolitic Imidazolate Frameworks and Their Microporous Glasses - From Melting Point Engineering to Selective Hydrocarbon Sorption.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b05558
Abstract: Porous glasses from metal-organic frameworks (MOFs) represent a new class of functional inorganic-organic glasses, which have been proposed for applications ranging from solid electrolytes to radioactive waste storage. So far, just a few zeolitic imidazolate… read more here.
Keywords: melting point; imidazolate frameworks; zif; imidazolate ... See more keywords
Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc02083g
Abstract: A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio… read more here.
Keywords: cubic cobalt; imidazolate cages; cobalt imidazolate; mixed valence ... See more keywords
Recent advancement of imidazolate framework (ZIF-8) based nanoformulations for synergistic tumor therapy.
Sign Up to like & getrecommendations! Published in 2019 at "Nanoscale"
DOI: 10.1039/c9nr06558j
Abstract: As a new kind of porous material, zeolitic imidazolate frameworks (ZIF-8) are built from zinc ions and 2-methylimidazolate and possess unique merits including high porosity, good structural regularity and tunability, adjustable surface functionality and intrinsic… read more here.
Keywords: therapy; advancement imidazolate; zif; recent advancement ... See more keywords
Metal imidazolate sulphate frameworks as a variation of zeolitic imidazolate frameworks.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc07046k
Abstract: Sulphate ions can be incorporated into zinc imidazolate frameworks to give rise to zinc imidazolate sulphate frameworks, that is, a square-grid network, a zeolite-like GIS framework, or a porous pillar-layered structure where interlayer octahedral Zn2+… read more here.
Keywords: imidazolate sulphate; imidazolate frameworks; imidazolate; sulphate frameworks ... See more keywords
Multivariate zeolitic imidazolate frameworks with an inverting trend in flexibility.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04362a
Abstract: Through systematic linker substitution in a flexible zeolitic imidazolate framework (ZIF) with step-shaped adsorption-desorption, structural intermediates between the known open and closed phases were isolated. Reflecting this, modulative sorption behaviour with an inverting adsorption pressure… read more here.
Keywords: imidazolate frameworks; imidazolate; multivariate zeolitic; flexibility ... See more keywords
Harnessing nanoscale spatial effects in inner-modified zeolitic imidazolate framework-8 for enhanced Knoevenagel condensation reaction
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d3qi02190d
Abstract: Metal–organic frameworks (MOFs) have played a pivotal role in catalysis, driven by their remarkable surface area and structural versatility. The structural manipulation of zeolitic imidazolate frameworks (ZIFs) has shed light... read more here.
Keywords: spatial effects; imidazolate; harnessing nanoscale; nanoscale spatial ... See more keywords