Control over the synthesis of homovalent and mixed-valence cubic cobalt-imidazolate cages.
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DOI: 10.1039/c9cc02083g
Abstract: A series of cubic cobalt-imidazolate cages have been successfully synthesized via subcomponent self-assembly in different solvents under solvothermal conditions. The homovalent CoII and mixed-valence CoIII,II-imidazolate cages are assembled with control over the mixed solvent ratio… read more here.
Keywords: cubic cobalt; imidazolate cages; cobalt imidazolate; mixed valence ... See more keywords