Safe and selective anticancer agents from tetrafluorinated azobenzene‐imidazolium ionic liquids: Synthesis, characterization, and cytotoxic effects
Sign Up to like & getrecommendations! Published in 2022 at "Archiv der Pharmazie"
DOI: 10.1002/ardp.202200085
Abstract: A new series of tetrafluorinated azobenzene‐imidazolium salts is reported. The azobenzene and imidazolium moieties were functionalized with long alkyl chains and connected via a methylene spacer of varying lengths (n = 3–12). They were characterized using FTIR… read more here.
Keywords: cytotoxic; azobenzene imidazolium; ionic liquids; tetrafluorinated azobenzene ... See more keywords
Synthesis of Imidazolium Oligomers with Planar and Stereo Cores and Their Antimicrobial Applications
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DOI: 10.1002/cmdc.201700167
Abstract: A series of imidazolium oligomers with novel planar and stereo core structures were designed and synthesized. These compounds have symmetric structures with different cores, tails, and linkers. These new imidazolium oligomers demonstrated a desirable set… read more here.
Keywords: imidazolium oligomers; oligomers planar; planar stereo; synthesis imidazolium ... See more keywords
Surface Enrichment in Equimolar Mixtures of Non‐Functionalized and Functionalized Imidazolium‐Based Ionic Liquids
Sign Up to like & getrecommendations! Published in 2018 at "Chemphyschem"
DOI: 10.1002/cphc.201800216
Abstract: Abstract For equimolar mixtures of ionic liquids with imidazolium‐based cations of very different electronic structure, we observe very pronounced surface enrichment effects by angle‐resolved X‐ray photoelectron spectroscopy (XPS). For a mixture with the same anion,… read more here.
Keywords: meo 2im; equimolar mixtures; surface enrichment; ionic liquids ... See more keywords
Periodic imidazolium-bridged hybrid monolith for high-efficiency capillary liquid chromatography with enhanced selectivity.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of separation science"
DOI: 10.1002/jssc.201601014
Abstract: A novel periodic imidazolium-bridged hybrid monolithic column was developed. With diene imidazolium ionic liquid 1-allyl-3-vinylimidazolium bromide as both cross-linker and organic functionalized reagent, a new periodic imidazolium-bridged hybrid monolithic column was facilely prepared in capillary… read more here.
Keywords: periodic imidazolium; column; imidazolium bridged; bridged hybrid ... See more keywords
A Multifunctional Imidazolium-Based Silicone Material with Conductivity, Self-Healing, Fluorescence, and Stretching Sensitivity.
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201900469
Abstract: Wearable devices have gained substantial interest for a wide range of applications, including biomonitoring and entertainment. They are basically composed of sensors and substrate materials. Recently, silicone materials have been extensively used in wearable devices… read more here.
Keywords: silicone material; conductivity; material; self healing ... See more keywords
Synthesis of Ti(OH)OF ⋅ 0.66 H2 O in Imidazolium-based Ionic Liquids.
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DOI: 10.1002/open.202000256
Abstract: The influence of the cation of imidazolium-derived ionic liquids (ILs) on a low-temperature solution-based synthesis of hexagonal tungsten bronze (HTB) type Ti(OH)OF ⋅ 0.66 H2 O and bronze-type TiO2 (B) is investigated. The IL (Cx mim BF4 ) acts… read more here.
Keywords: mim bf4; reaction; ionic liquids; synthesis ... See more keywords
Reactivity and Controlled Redox Reactions of Salt-like Intermetallic Compounds in Imidazolium-Based Ionic Liquids.
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DOI: 10.1002/open.202000262
Abstract: Substituted imidazolium ionic liquids (ILs) were investigated for their reactivity towards Na12 Ge17 as a model system containing redox-sensitive Zintl cluster anions. The ILs proved widely inert for imidazolium cations with a 1,2,3-trisubstitution at least… read more here.
Keywords: na12 ge17; reactivity; salt like; ionic liquids ... See more keywords
As Catalytic as Silver Nanoparticles Anchored to Reduced Graphene Oxide: Fascinating Activity of Imidazolium Based Surface Active Ionic Liquid for Chemical Degradation of Rhodamine B
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DOI: 10.1007/s10562-019-02798-4
Abstract: A kinetic study, first of its kind, regarding the catalytic activity of imidazolium-based surface-active ionic liquid (SAIL) viz. 1-dodecyl-3-methyl imidazolium chloride ([DDMIM][Cl]) toward the reductive degradation of a model cationic dye viz. rhodamine B (RhB)… read more here.
Keywords: degradation; active ionic; ionic liquid; catalytic activity ... See more keywords
Removal of imidazolium- and pyridinium-based ionic liquids by Fenton oxidation
Sign Up to like & getrecommendations! Published in 2018 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-017-0867-4
Abstract: AbstractThe oxidation of imidazolium (1-hexyl-3-methylimidazolium chloride, HmimCl) and pyridinium (1-butyl-4-methylpyridinium chloride, BmpyrCl) ionic liquids (ILs) by Fenton’s reagent has been studied. Complete conversion was achieved for both ILs using the stoichiometric H2O2 dose at 70 °C,… read more here.
Keywords: oxidation; imidazolium pyridinium; removal; ionic liquids ... See more keywords
Evaluation of the impact of different alkyl length and type of substituent in imidazolium ionic liquids on cucumber germination, growth and oxidative stress
Sign Up to like & getrecommendations! Published in 2018 at "Environmental Science and Pollution Research"
DOI: 10.1007/s11356-018-3534-5
Abstract: In this work, the effect on cucumber growth of seven different imidazolium-based ionic liquids, namely 1-(2-oxybutyl)-3-methylimidazolium chloride, [C2OC2mIm][Cl]; 1-(2-oxypropyl)-3-methylimidazolium chloride, [C1OC2mIm][Cl]; 1-(3-hydroxypropyl)-3-ethylimidazolium chloride, [OHC3eIm][Cl]; 1-(3-hydroxypropyl)-3-methylimidazolium chloride, [OHC3mIm][Cl]; 1-(2-hydroxyethyl)-3-methylimidazolium chloride, [OHC2mIm][Cl], 1-butyl-3-methylimidazolium chloride, [bmim][Cl] and imidazolium… read more here.
Keywords: methylimidazolium chloride; chloride; ionic liquids; growth ... See more keywords
Rapid proton diffusion in hydroxyl functionalized imidazolium ionic liquids
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DOI: 10.1007/s11426-016-0459-2
Abstract: There is considerable interest in using ionic liquids (ILs) as protic electrolytes. However, the reported proton transfer rate in ILs is quite slow. In this study, we report functionalizing imidazolium ILs with alcohol hydroxyls, aiming… read more here.
Keywords: diffusion; rapid proton; proton; hydrogen bonding ... See more keywords