Surface Enrichment in Equimolar Mixtures of Non‐Functionalized and Functionalized Imidazolium‐Based Ionic Liquids
Sign Up to like & getrecommendations! Published in 2018 at "Chemphyschem"
DOI: 10.1002/cphc.201800216
Abstract: Abstract For equimolar mixtures of ionic liquids with imidazolium‐based cations of very different electronic structure, we observe very pronounced surface enrichment effects by angle‐resolved X‐ray photoelectron spectroscopy (XPS). For a mixture with the same anion,… read more here.
Keywords: meo 2im; equimolar mixtures; surface enrichment; ionic liquids ... See more keywords
Imidazolium Based Ionic Liquids as Electrolytes for Energy Efficient Electrical Double Layer Capacitor: Insights from Molecular Dynamics and Electrochemical Characterization
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Solution Chemistry"
DOI: 10.1007/s10953-019-00898-8
Abstract: Ionic liquids (ILs) have attracted considerable interest as electrolytes for electrical double layer capacitors (EDLC) bringing in enhancement of energy efficiency. This work studied three imidazolium based ILs mixed with a co-solvent as the electrolytes… read more here.
Keywords: electrical double; energy; double layer; tf2n ... See more keywords
Cation influence of new imidazolium-based ionic liquids on hydrogen production from water electrolysis
Sign Up to like & getrecommendations! Published in 2018 at "Ionics"
DOI: 10.1007/s11581-018-2803-0
Abstract: AbstractAqueous solutions of three new imidazolium-based ionic liquids, imidazolium hydrogenosulfate, methylimidazolium hydrogenosulfate, and butylimidazolium hydrogenosulfate, have been tested as electrolytes in the hydrogen evolution reaction (HER) by water electrolysis. Tafel analyses have been conducted on… read more here.
Keywords: water electrolysis; new imidazolium; ionic liquids; based ionic ... See more keywords
Physiological and biochemical responses of wheat (Triticum aestivum L.) seedlings to three imidazolium-based ionic liquids in soil.
Sign Up to like & getrecommendations! Published in 2018 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2017.09.108
Abstract: Ionic liquids (ILs) are considered environmentally friendly solvents and are widely applied in various fields; however, some researchers have noted the toxicity of ILs to plants cultivated in nutrient solution. To evaluate the toxicities of… read more here.
Keywords: wheat seedlings; c8mim; three imidazolium; soil ... See more keywords
Experimental and theoretical studies of four allyl imidazolium-based ionic liquids as green inhibitors for copper corrosion in sulfuric acid
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DOI: 10.1016/j.corsci.2017.02.021
Abstract: Abstract In this work, four allyl imidazolium-based ionic liquids (ILs) with various length of alkyl chains were developed for the corrosion inhibition of copper in 0.5 M sulfuric acid. Electrochemical techniques, morphological characterization, theoretical caculations were… read more here.
Keywords: four allyl; allyl imidazolium; corrosion; based ionic ... See more keywords
DFT study of fructose dehydration to 5-hydroxymethylfurfural catalyzed by imidazolium-based ionic liquid
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Physics Letters"
DOI: 10.1016/j.cplett.2019.03.047
Abstract: Abstract DFT calculations have been performed to gain insight into the mechanism of production 5-hydroxymethylfurfural (HMF) from fructose catalyzed by a representative imidazolium-based ionic liquid (IL), 1-butyl-3-methyl-imidazolium bromide ([BMIM]Br). The overall barrier of the catalytic… read more here.
Keywords: dehydration; based ionic; imidazolium; imidazolium based ... See more keywords
Insights into the effect of the spacer on the properties of imidazolium based AIE luminogens
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DOI: 10.1016/j.dyepig.2020.109035
Abstract: Abstract With the aim to obtain organic salts with potential applications in high performance molecular electronics, we combined properties of π-conjugated spacers, like 1,4-diethynylbenzene and 1,6-diethynylpyrene, with the ones of both imidazole and imidazolium units.… read more here.
Keywords: spacer properties; properties imidazolium; insights effect; effect spacer ... See more keywords
Moderate halophilic bacteria, but not extreme halophilic archaea can alleviate the toxicity of short-alkyl side chain imidazolium-based ionic liquids.
Sign Up to like & getrecommendations! Published in 2019 at "Ecotoxicology and environmental safety"
DOI: 10.1016/j.ecoenv.2019.109634
Abstract: Imidazolium-based ionic liquids (IL) with short-alkyl side chain such as 1-ethyl-3-methyl-imidazolium chloride ([Emim]Cl) and 1-butyl-3-methyl-imidazolium chloride ([Bmim]Cl) has immense application potential including in lignocellulosic bioenergy production. But they are toxic to most microorganisms, and those… read more here.
Keywords: archaea; moderate halophilic; ionic liquids; based ionic ... See more keywords
Operando STM study of the interaction of imidazolium-based ionic liquid with graphite
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DOI: 10.1016/j.ensm.2018.11.026
Abstract: Abstract Understanding interactions at the interfaces of carbon with ionic liquids (ILs) is crucially beneficial for the diagnostics and performance improvement of electrochemical devices containing carbon as active materials or conductive additives in electrodes and… read more here.
Keywords: stm; imidazolium based; stm study; graphite ... See more keywords
Separation of acetonitrile + ethanol mixture using imidazolium - Based ionic liquids as entrainers
Sign Up to like & getrecommendations! Published in 2018 at "Fluid Phase Equilibria"
DOI: 10.1016/j.fluid.2018.06.017
Abstract: Abstract Three imidazolium-based ionic liquids: 1-methy-3-methylimidazolium dimethylphosphate ([MMIM][DMP]), 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][DEP]) and 1-butyl-3-methylimidazolium dibutylphosphate ([BMIM][DBP]) were used as entrainers to separate acetonitrile + ethanol mixtures. Isobaric vapor-liquid equilibrium (VLE) data were measured at 101.3 kPa. Addition of ionic… read more here.
Keywords: separation acetonitrile; acetonitrile ethanol; ionic liquids; based ionic ... See more keywords
Structural-functional integrity of lysozyme in imidazolium based surface active ionic liquids.
Sign Up to like & getrecommendations! Published in 2020 at "International journal of biological macromolecules"
DOI: 10.1016/j.ijbiomac.2020.04.033
Abstract: The present study was designed to explore the hydrophobicity and concentration dependence of imidazolium based surface active ionic liquids (SAILs) effects on the structural-functional integrity of proteins. Specifically, we investigated the impact of SAILs viz.… read more here.
Keywords: based surface; omim dbs; dbs; concentration ... See more keywords