Controlling Diradical Character of Photogenerated Colored Isomers of Phenoxyl-Imidazolyl Radical Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07562
Abstract: We propose a rational method for evaluating the diradical character of the photochromic phenoxyl-imidazolyl radical complex (PIC) derivatives based on their radical-radical coupling reaction rates. PIC consists of an imidazole ring, a phenoxyl ring, and… read more here.
Keywords: imidazolyl radical; ring isomer; character; phenoxyl imidazolyl ... See more keywords
A photochromic carbazolyl-imidazolyl radical complex.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01196d
Abstract: A carbazole-incorporated photochromic radical complex is synthesized. The long-wavelength photosensitivity of the photochromic reaction of the molecule is enhanced up to ∼580 nm by substituting a triphenylamine group into the 3-position of the carbazole moiety.… read more here.
Keywords: radical complex; carbazolyl imidazolyl; imidazolyl radical; photochromic carbazolyl ... See more keywords