Lewis Base-Enhanced C–H Bond Functionalization Mediated by a Diiron Imido Complex
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DOI: 10.1021/acs.inorgchem.4c03922
Abstract: Herein, we investigate the effects of ligand design on the nuclearity and reactivity of metal–ligand multiply bonded (MLMB) complexes to access an exclusively bimetallic reaction pathway for C–H bond functionalization. To this end, the diiron… read more here.
Keywords: fe2 phdbf; imido complex; bond functionalization; diiron imido ... See more keywords
Computational Analysis of the Intramolecular Oxidative Amination of an Alkene Catalyzed by the Extreme π-Loading N-Heterocyclic Carbene Pincer Tantalum(V) Bis(imido) Complex
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DOI: 10.1021/acs.organomet.8b00097
Abstract: The extreme π-loading of a (CCC-NHC) pincer Ta(V) bis(imido) complex was previously reported. This complex catalyzes the cyclization of α,ω-aminoalkenes (2,2-diphenylpent-4-en-1-amine) to produce three different products in varying proportions: cyclic imine from oxidative amination (OA),… read more here.
Keywords: imido complex; oxidative amination; extreme loading; product ... See more keywords