Redox-Controlled and Reversible N-N Bond Forming and Splitting with an IronIV Terminal Imido Ligand.
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DOI: 10.1021/acs.inorgchem.1c01509
Abstract: Oxidation of the low-spin FeIV imido complex [{(tBupyrr)2py}Fe═NAd] (1) ((tBupyrr)2py2- = 2,6-bis(3,5-di-tert-butyl-pyrrolyl)pyridine, Ad = 1-adamantyl) with AgOAc or AgNO3 promotes reductive N-N bond coupling of the former imido nitrogen with a pyrrole nitrogen to form… read more here.
Keywords: imido; bond; tbupyrr; imido ligand ... See more keywords