Elemental chalcogen reactions of a tetravalent uranium imidophosphorane complex: cleavage of dioxygen.
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DOI: 10.1039/d2cc05066h
Abstract: Herein we report the first example of a mononuclear uranium complex, [U4+(NP(pip)3)4] (1-U), that selectively reduces dioxygen to produce a terminal oxo complex, [U6+O(NP(pip)3)4] (2-U; [NP(pip)3]1- is tris(piperidinyl)imidophosphorane). Reactions between 1-U and the heavier elemental… read more here.
Keywords: elemental chalcogen; dioxygen; imidophosphorane; reactions tetravalent ... See more keywords