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Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01349
Abstract: We have achieved a facile access to N-(2-halophenyl)-2-hydroxyphenylimine derivatives via imine anion-mediated Smiles rearrangement. When 2-(2-halophenoxy)benzonitriles were treated with 1.2-1.4 equiv of organolithium reagents, nucleophilic addition to the nitrile group followed by Smiles rearrangement occurred…
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Keywords:
smiles rearrangement;
imine anion;
anion mediated;
access ... See more keywords