Alkoxylation of the imine carbon atom of a Schiff-base ligand upon coordination to arene ruthenium
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.07.025
Abstract: Abstract The Schiff-base 5-methyl-4-{(pyridin-2-ylmethylene)amino}-4H-1,2,4-triazole-3-thiol (L-H) reacts in alcoholic solution (methanol, ethanol, isopropanol) at room temperature with the dinuclear precursor [(η6-MeC6H4Pri)RuCl2]2 to give a series of neutral complexes of the general formula (η6-MeC6H4Pri)Ru(L-OR) (R = Me, 1; R = Et,… read more here.
Keywords: ruthenium; carbon; imine carbon; ligand ... See more keywords
Computational study on the NHC-catalyzed synthesis of 2,3-disubstituted indoles: mechanism, key intermediate and the role of the catalyst
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DOI: 10.1039/c8qo00139a
Abstract: In this work, the possible reaction mechanisms and the role of N-heterocyclic carbene (NHC) catalysts in the umpolung reaction of imines to generate 2-substituted indole-3-acetic acid derivatives were investigated by density functional theory (DFT). Two… read more here.
Keywords: carbon; unsaturated ester; carbon unsaturated; imine carbon ... See more keywords