Chiral Magnesium(II)-Catalyzed Asymmetric Hydroalkylation of Imine-Containing Vinylazaarenes through Conjugate Addition.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c00668
Abstract: The synthesis of chiral azaarenes is of great importance for pharmaceutical development. A direct and versatile approach to obtaining such compounds is the functionalization of imine-containing 2-vinylazaarenes. We have developed a chiral N,N'-dioxide/Mg(II) Lewis acid… read more here.
Keywords: hydroalkylation imine; imine containing; containing vinylazaarenes; conjugate addition ... See more keywords
Hydrazone- and imine-containing [PdPtL4]4+ cages: a comparative study of the stability and host-guest chemistry.
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DOI: 10.1039/d2dt02720h
Abstract: A new [PdPtL4]4+ heterobimetallic cage containing hydrazone linkages has been synthesised using the sub-component self-assembly approach. 1H and DOSY nuclear magnetic resonance (NMR) spectroscopy and electrospray ionisation mass spectrometry (ESIMS) data were consistent with the… read more here.
Keywords: host guest; cage; chemistry; containing pdptl4 ... See more keywords
N,N′,N′′ versus N,N′,O imine-containing coordination motifs: ligand-directed synthesis of mononuclear and binuclear CuII compounds
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DOI: 10.1107/s2056989017013652
Abstract: It is shown that tridentate imine ligands can control the nuclearity of copper(II) complexes based on the donor atoms present in the ligand. While the N,N′,N′′-donating imine ligand led to a mononuclear compound, the N,N′,O-donating… read more here.
Keywords: coordination motifs; imine containing; containing coordination; ligand directed ... See more keywords