Polyoxometalate catalyzed imine synthesis: Investigation of mechanistic pathways
Sign Up to like & getrecommendations! Published in 2020 at "Tetrahedron"
DOI: 10.1016/j.tet.2020.131245
Abstract: Abstract The syntheses of imines by oxidative coupling of primary alcohols and amines were achieved by using 2 mol% polyoxometalate (POM) Na12[WZn3(H2O)2(ZnW9O34)2] (Zn–WZn3) catalyst in the presence of t-BuOK and di-oxygen with excellent conversion (up to… read more here.
Keywords: polyoxometalate catalyzed; investigation mechanistic; synthesis investigation; imine synthesis ... See more keywords
One-pot imine synthesis from methylarenes and anilines under air over heterogeneous Cu oxide-modified CeO2 catalyst.
Sign Up to like & getrecommendations! Published in 2020 at "Chemical communications"
DOI: 10.1039/d0cc02969f
Abstract: Cu oxide-modified CeO2 (CuOx-CeO2) with 2 wt% Cu loading amount was the most effective and reusable heterogeneous catalyst for selective one-pot imine synthesis from methylarenes and anilines via direct oxidation of the sp3 C-H bond… read more here.
Keywords: pot imine; one pot; synthesis methylarenes; imine synthesis ... See more keywords