Hydroboration of Imines and Alkynes Catalyzed by Electronically Unsaturated Aluminum Hydride and Methyl Aluminum Cations.
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DOI: 10.1021/acs.inorgchem.2c03775
Abstract: Aluminum hydride cations, [LAlH]+[HB(C6F5)3]- (1) and [LAlH]+[B(C6F5)4]- (2), and the methyl aluminum cation, [LAlMe]+[B(C6F5)4]- (3) (L = [{(2,6-iPr2C6H3N)P(Ph2)}2N]), due to their electronic and coordinative unsaturation at the Al center, exhibit high Lewis acidity and have… read more here.
Keywords: imines alkynes; aluminum; hydroboration imines; methyl aluminum ... See more keywords