Direct catalytic enantioselective Mannich-type reaction of α,α-dithioacetonitriles with imines using chiral bis(imidazoline)-Pd complexes.
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DOI: 10.1039/c7cc03307a
Abstract: The first highly enantioselective reaction of α,α-dithioacetonitriles with imines has been developed. Good yields and enantioselectivity were observed for the reaction of various imines using chiral bis(imidazoline) catalysts. The obtained products can be converted into… read more here.
Keywords: reaction dithioacetonitriles; chiral bis; reaction; imines using ... See more keywords