Mononuclear manganese(iii) complexes with reduced imino nitroxide radicals by single-electron transfer and intermolecular hydrogen bonds as an intramolecular structural driving force.
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DOI: 10.1039/c9dt02158b
Abstract: Manganese(iii) complexes were synthesized by one-electron transfer from a Mn(ii) ion to the imino nitroxide radical 2-(2-imidazolyl)-4,4,5,5-tetramethylimidazoline-1-oxyl (IMImH) in methanol. After the manganese ions attained the +III oxidation state, the imino nitroxide radicals were found… read more here.
Keywords: iii; manganese iii; nitroxide radicals; electron transfer ... See more keywords