New efficient tetraphenyl silylated poly(azomethine)s based on “pincer-like” bis(imino)pyridine iron(III) complexes as heterogeneous catalysts for CO2 conversion
Sign Up to like & getrecommendations! Published in 2020 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2020.109567
Abstract: Abstract Aromatic poly(azomethine)s containing simultaneously for the first time both tetraphenyl silane moeties and “pincers” of bis(imino)pyridine were prepared, to provide these polymers with a robust structure and ability to anchor metals. The polymers were… read more here.
Keywords: heterogeneous catalysts; imino pyridine; bis imino; conversion ... See more keywords
Mechanistic Investigation of Bis(imino)pyridine Manganese Catalyzed Carbonyl and Carboxylate Hydrosilylation.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b00879
Abstract: We recently reported a bis(imino)pyridine (or pyridine diimine, PDI) manganese precatalyst, (Ph2PPrPDI)Mn (1), that is active for the hydrosilylation of ketones and dihydrosilylation of esters. In this contribution, we reveal an expanded scope for 1-mediated… read more here.
Keywords: imino pyridine; bis imino; carboxylate hydrosilylation; catalyzed carbonyl ... See more keywords