Articles with "iminophosphorane superbases" as a keyword



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Bifunctional iminophosphorane superbases: Potent organocatalysts for enantio- and diastereoselective Michael addition reactions

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Published in 2018 at "Tetrahedron"

DOI: 10.1016/j.tet.2018.06.021

Abstract: Abstract Bifunctional iminophosphorane (BIMP) organocatalysts catalyze the enantio- and diastereoselective Michael additions of high pKa cyclic malonamate ester pro-nucleophiles to nitroalkenes with reactivity profiles of up to 3 orders of magnitude greater than tertiary amine… read more here.

Keywords: iminophosphorane superbases; enantio diastereoselective; bifunctional iminophosphorane; diastereoselective michael ... See more keywords