The Implications of the Brønsted Acidic Properties of Crabtree-Type Catalysts in the Asymmetric Hydrogenation of Olefins
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DOI: 10.1021/jacs.2c07023
Abstract: Chiral iridium complexes derived from Crabtree’s catalyst are highly useful in modern hydrogenations of olefins attributed to high reactivity, stereoselectivity, and stability. Despite that these precatalysts are pH neutral, the reaction mixtures turn acidic under… read more here.
Keywords: hydrogenation olefins; acidic properties; implications nsted; hydrogenation ... See more keywords