Inclusion and reactivity of main group radicals in the porous framework MIL-53(Al).
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DOI: 10.1039/c9dt03624e
Abstract: Inclusion of the dithiadiazolyl and diselenadiazolyl radicals PhCNEEN (E = S, Se) into the porous framework, Al(bdc)(OH) [MIL-53(Al); bdc = 1,4-benzenedicarboxylate] was achieved by vacuum sublimation. PXRD studies reveal the inclusion complexes adopt the orthorhombic… read more here.
Keywords: inclusion reactivity; framework; porous framework; group ... See more keywords