Boosting the Thermal Stability of α-Diimine Palladium Complexes in Norbornene Polymerization from Construction of Intraligand Hydrogen Bonding and Simultaneous Increasing Axial/Equatorial Bulkiness.
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DOI: 10.1021/acs.inorgchem.0c03185
Abstract: Increasing the thermostability of α-diimine late-transition-metal complexes and therefore rendering them more active at higher temperatures is of great importance, yet challenging for the olefin polymerization field. In the present research, a new family of… read more here.
Keywords: polymerization; palladium complexes; diimine palladium; diimine ... See more keywords