Study on 1,4-hydride shift triggered spirocyclization of arylidene imidazolones: substituent control on formation of indane or tetrahydrobenzazepine systems
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DOI: 10.71267/mencom.7550
Abstract: A rare process of 1,4-hydride or formal 1,6-hydride shift occurs in the (o-dialkylaminomethyl)arylidene imidazolones under the action of aluminum chloride. Only sterically hindered amino derivatives are able to enter the spirocyclization reaction, and the substituent… read more here.
Keywords: arylidene imidazolones; hydride shift; indane; study hydride ... See more keywords