Bonding and electronic structures in dinuclear (X)[(Ind)M2L2] complexes (M = Ni, Pd, L = CO, PEt3, X = Cl, Allyl, Ind = indenyl, Cp = cyclopentadienyl): analogy between four-electron donor ligands
Sign Up to like & getrecommendations! Published in 2019 at "Theoretical Chemistry Accounts"
DOI: 10.1007/s00214-019-2526-y
Abstract: The calculations of bimetallic complexes of the type (X)[(Ind)M2(L)2] (M = Ni, Pd, L = CO, (PEt3) and X = Allyl, Cp and indenyl) have been done using two DFT functionals, namely BP86 and B3LYP*. The allyl, Cp and indenyl ligands… read more here.
Keywords: ind; indenyl; pet3 allyl; metal ... See more keywords
(Indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11): synthesis, structure, and bonding
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DOI: 10.1007/s11172-017-1738-3
Abstract: A reaction of iodide [(η5-indenyl)IrI2]n (1) with thallium dicarbollide Tl[Tl(η-7,8-C2B9H11)] leads to (indenyl)iridacarborane (η5-indenyl)Ir(η-7,8-C2B9H11) (2) in 32% yield. The X-ray diffraction study showed that in the structure of 2, the five-membered rings C5 and C2B3… read more here.
Keywords: indenyl; iridacarborane indenyl; structure; indenyl iridacarborane ... See more keywords
Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
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DOI: 10.1021/acs.organomet.8b00311
Abstract: An efficient protocol for synthesis of indenyl rhodium complexes with arene ligands has been developed. The hexafluoroantimonate salts [(η5-indenyl)Rh(arene)](SbF6)2 (arene = benzene (2a), o-xylene (2b), mesitylene (2c), durene (2d), hexamethylbenzene (2e), and [2.2]paracyclophane (2g)) were… read more here.
Keywords: indenyl; rhodium complexes; indenyl rhodium; arene ligands ... See more keywords
Designing a Planar Chiral Rhodium Indenyl Catalyst for Regio- and Enantioselective Allylic C-H Amidation.
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DOI: 10.1021/jacs.0c07305
Abstract: Chiral variants of group IX Cp and Cp* catalysts are well established and catalyze a broad range of reactions with high levels of enantioselectivity. Enantiocontrol in these systems results from ligand design that focuses on… read more here.
Keywords: indenyl; rhodium; allylic amidation; catalyst ... See more keywords
Cationic palladium(II)-indenyl complexes bearing phosphines as ancillary ligands: synthesis, and study of indenyl amination and anticancer activity.
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DOI: 10.1039/d2dt01821g
Abstract: The reactivity of palladium(II) indenyl derivatives and their applications are topics relatively less studied, though in recent times these compounds have been used as pre-catalysts able to promote challenging cross-coupling processes. Herein, we propose the… read more here.
Keywords: indenyl; indenyl complexes; complexes bearing; palladium ... See more keywords