Asymmetric Induction via the Structural Indenyl Effect
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DOI: 10.1021/acs.organomet.7b00841
Abstract: Constrained geometry, planar chiral, dichloro[η5:κS-indenyl-sulfanyl]rhodium complex (pS)-1 reacts with (E)-2-pentene in the presence of silver hexafluoroantimonate to afford syn,syn-1,3-dimethyl-π-allyl complex (pS)-2 in 88% yield. Reaction of (pS)-2 with the sodium or tetrabutylammonium salts of dimethyl… read more here.
Keywords: indenyl effect; via structural; structural indenyl; asymmetric induction ... See more keywords