Indium‐Mediated Reductive Coupling Reactions
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DOI: 10.1002/cctc.202402162
Abstract: Indium, a main‐group metal, has unique chemical characteristics that allow it to lose one or three electrons to generate indium ionic compounds or organoindium compounds due to its low reduction potential and large atomic radius.… read more here.
Keywords: indium; indium mediated; reductive coupling; coupling reactions ... See more keywords
Palladium-catalyzed indium-mediated reductive aromatic C-H allylation of N-benzylsulfonimides with allyl esters.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc00881a
Abstract: An unprecedented reductive aromatic C-H allylation reaction of benzyl electrophiles with allyl electrophiles has been established. A range of N-benzylsulfonimides smoothly participated in the palladium-catalyzed indium-mediated reductive aromatic C-H allylation with various allyl acetates, delivering… read more here.
Keywords: aromatic allylation; reductive aromatic; catalyzed indium; palladium catalyzed ... See more keywords
Indium-mediated C-allylation of melibiose
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DOI: 10.3762/bjoc.15.238
Abstract: The indium-mediated allylation reaction has been applied to melibiose, a disaccharidic substrate. This elongation methodology allows for a short, efficient and diastereoselective approach towards complex glycosylated carbohydrate structures. The stereochemical outcome of the key intermediates,… read more here.
Keywords: mediated allylation; methodology; indium mediated; allylation melibiose ... See more keywords