Palladium-Catalyzed Asymmetric Nitrogen-Selective Addition Reaction of Indoles to Alkoxyallenes.
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DOI: 10.1021/acs.orglett.8b00191
Abstract: A new palladium-catalyzed asymmetric addition reaction of indoles to alkoxyallenes is reported. Remarkably, the reaction showed complete regioselectivity toward the nitrogen. A new mechanism distinct from that of conventional π-allyl chemistry is proposed to explain… read more here.
Keywords: catalyzed asymmetric; reaction indoles; indoles alkoxyallenes; palladium catalyzed ... See more keywords