Articles with "indolyl copper" as a keyword



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Catalytic Asymmetric [3 + 2] Annulation via Indolyl Copper-Allenylidene Intermediates: Diastereo- and Enantioselective Assembly of Pyrrolo[1,2-a]indoles.

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Published in 2020 at "Organic letters"

DOI: 10.1021/acs.orglett.0c01594

Abstract: A catalytic asymmetric decarboxylative [3 + 2] annulation via indolyl copper-allenylidene amphiphilic intermediates has been developed. This protocol offers a straightforward method for the synthesis of biologically important pyrrolo[1,2-a]indoles bearing contiguous quaternary and tertiary stereogenic… read more here.

Keywords: pyrrolo; pyrrolo indoles; annulation via; indolyl copper ... See more keywords