Coordination-Induced Bond Weakening.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.2c00254
Abstract: Coordination-induced bond weakening is a phenomenon wherein ligand X-H bond homolysis occurs in concert with the energetically favorable oxidation of a coordinating metal complex. The coupling of these two processes enables thermodynamically favorable proton-coupled electron… read more here.
Keywords: coordination induced; bond weakening; induced bond; bond ... See more keywords
Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00471
Abstract: The synthesis and characterization of a cationic molybdenum pyrrolidine complex are described that exhibits significant coordination-induced N–H bond weakening. The N–H bond dissociation free energ... read more here.
Keywords: pyrrolidine complex; induced bond; bond; molybdenum pyrrolidine ... See more keywords
Coordination-induced O-H bond weakening in Sm(ii)-water complexes.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03352a
Abstract: The combination of Sm(ii)-based reductants with water provides reagent systems that promote a range of reductions and bond-forming reactions that are endergonic based on known redox potentials. Despite the utility of these reagent systems, little… read more here.
Keywords: induced bond; water; bond; bond weakening ... See more keywords
The molecular mechanism of light-induced bond formation and breakage in the cyanobacteriochrome TePixJ
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DOI: 10.1039/d2cp05856a
Abstract: Cyanobacteriochromes (CBCRs) are small and versatile photoreceptor proteins with high potential for biotechnological applications. Among them, the so-called DXCF-CBCRs exhibit an intricate secondary photochemistry: miliseconds after activation with light, a covalent linkage between a conserved… read more here.
Keywords: light induced; induced bond; spectroscopy; bond formation ... See more keywords
The mechanism of Fe induced bond stability of uranyl(v)
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DOI: 10.1039/d2sc03416f
Abstract: The stabilization of uranyl(v) (UO21+) by Fe(ii) in natural systems remains an open question in uranium chemistry. Stabilization of UVO21+ by Fe(ii) against disproportionation was also demonstrated in molecular complexes. However, the relation between the… read more here.
Keywords: induced bond; stability uranyl; stability; bond stability ... See more keywords