Visible photo-induced catalyst-free polymerization via in situ prepared dibromide
Sign Up to like & getrecommendations! Published in 2020 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2020.110195
Abstract: Abstract In situ bromination of vinyl monomers with tetra-n-butyl ammonium tribromide and irradiation of the corresponding dibromide upon exposure to visible-LED (λ=400 nm) followed by C-Br bond photocleavage, successfully synthesis of polystyrene, polyacrylamide and the… read more here.
Keywords: photo; photo induced; visible photo; free polymerization ... See more keywords
Chirality-Induced Catalyst Aggregation: Insights into Catalyst Speciation and Activity Using Chiral Aluminum Catalysts in Cyclic Ester Ring-Opening Polymerization
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DOI: 10.1021/acscatal.0c05245
Abstract: A series of chiral-at-metal aluminum complexes have been synthesized using chiral catam ligands. Reactivity studies demonstrate the importance of alkoxide bulkiness and complex chirality in inducin... read more here.
Keywords: chirality induced; catalyst aggregation; aluminum; induced catalyst ... See more keywords