Switchable C–H Silylation of Indoles Catalyzed by a Thermally Induced Frustrated Lewis Pair
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DOI: 10.1021/acscatal.8b01847
Abstract: It is a challenging task to achieve regioselective C–H silylation of indoles with Ph2SiH2, as bis(indol-3-yl)-substituted silanes are always obtained along with the C3-silylated indoles. Without adding any additive, we developed an Al(C6F5)3-based catalyst system… read more here.
Keywords: silylation; induced frustrated; lewis pair; thermally induced ... See more keywords