Design of bond-cleavage-induced intramolecular charge transfer emission with dibenzoboroles and their application to ratiometric sensors for discriminating chain lengths of alkanes
Sign Up to like & getrecommendations! Published in 2017 at "Materials Chemistry Frontiers"
DOI: 10.1039/c7qm00350a
Abstract: Dibenzoborole derivatives containing four-coordinated boron were designed to realize emission from the bond-cleavage-induced intramolecular charge transfer (BICT) transition. A series of electron-donating and accepting groups were introduced into dibenzoborole through regioselective bromination and Suzuki–Miyaura coupling… read more here.
Keywords: cleavage induced; intramolecular charge; bond cleavage; induced intramolecular ... See more keywords
NBS-induced intramolecular annulation reactions for the divergent synthesis of fused- and spirocyclic indolines.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01920a
Abstract: An NBS-induced intramolecular annulation of 3-(1H-indol-3-yl)-N-alkoxypropanamide is described. The reactions proceed well and quickly under mild conditions with the help of a base. It was found that C2-substituents on the indole ring in 3-(1H-indol-3-yl)-N-alkoxypropanamide have… read more here.
Keywords: nbs induced; intramolecular annulation; induced intramolecular; divergent synthesis ... See more keywords