Nucleophile induced ligand rearrangement reactions of alkoxy- and arylsilanes
Sign Up to like & getrecommendations! Published in 2019 at "Tetrahedron"
DOI: 10.1016/j.tet.2019.04.062
Abstract: Abstract The ligand-redistribution reactions of aryl- and alkoxy-hydrosilanes can potentially cause the formation of gaseous hydrosilanes, which are flammable and pyrophoric. The ability of generic nucleophiles to initiate the ligand-redistribution reaction of commonly used hydrosilane… read more here.
Keywords: induced ligand; reactions alkoxy; ligand rearrangement; ligand redistribution ... See more keywords
Sterically Induced Ligand Framework Distortion Effects on Catalytic Cyclic Ester Polymerizations.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00250
Abstract: Aluminum alkoxide complexes supported by salen ligands [salen = N, N'-bis(salicylaldimine)-2-methylpropane-1,2-diamine or N, N'-bis(salicylaldimine)-2,2-dimethylpropane-1,3-diamine] with o-adamantyl substituents have been synthesized and investigated for the polymerization of ε-caprolactone. Geometric analysis of the catalysts used for the… read more here.
Keywords: framework distortion; distortion effects; sterically induced; induced ligand ... See more keywords
Giant Magnetic Anisotropy Induced by Ligand LS Coupling in Layered Cr Compounds.
Sign Up to like & getrecommendations! Published in 2019 at "Physical review letters"
DOI: 10.1103/physrevlett.122.207201
Abstract: We propose a novel origin of magnetic anisotropy to explain the unusual magnetic behaviors of layered ferromagnetic Cr compounds (3d^{3}) wherein the anisotropy field varies from ≲0.01 to ∼3 T on changing the ligand atom in… read more here.
Keywords: induced ligand; anisotropy; anisotropy induced; magnetic anisotropy ... See more keywords