Molybdenum Trihydride Complexes: Computational Model of Oxidatively Induced Reductive Elimination of Dihydrogen.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02805
Abstract: Recent experimental work shows that the 18-electron molybdenum complexes (1,2,4-C5H2tBu3)Mo(PMe3)2H3 (CptBuMoH3) and (C5HiPr4)Mo(PMe3)2H3 (CpiPrMoH3) undergo oxidatively induced reductive elimination of dihydrogen (H2), slowly forming the 15-electron monohydride species in tetrahydrofuran and acetonitrile. The 17-electron [CptBuMoH3]+… read more here.
Keywords: induced reductive; oxidatively induced; cptbumoh3; cpiprmoh3 ... See more keywords
Coordination-induced reductive elimination from a titanium(IV) complex.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc02500h
Abstract: Diamidopyridine-supported titanium dibenzyl complexes undergo coordination-induced C-C reductive elimination upon addition of alkynes and quantitative formation of titanacyclopentadienes. The distinct radical mechanism of this reductive mechanism gives new insights into C-C bond formation with titanium. read more here.
Keywords: reductive elimination; coordination induced; titanium; induced reductive ... See more keywords