Visible-Light-Induced Regioselective Functionalization of α-Olefin: Development of One-Pot Photo-Synthesis of C3-Substituted Dihydrobenzofurans.
Sign Up to like & getrecommendations! Published in 2023 at "Organic letters"
DOI: 10.1021/acs.orglett.3c00335
Abstract: A method for the catalytic regioselective synthesis of C3-substituted dihydrobenzofurans (DHBs) via [2 + 2] photocycloaddition of alkene and p-benzoquinone is developed. This method realizes the rapid synthesis of DHBs with readily available substrates and… read more here.
Keywords: induced regioselective; light induced; synthesis substituted; synthesis ... See more keywords
Iridium-induced regioselective B-H and C-H activations at azo-substituted m-carboranes: facile access to polynuclear complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc09084j
Abstract: Iridium(iii)-induced selective B(2,3)-H and C-H bond activations at mono- and bi-p-methoxybenzeneazo-substituted m-carboranes have been investigated. A powerful methodology is introduced for the preparation of unique polynuclear complexes featuring m-carboranyl ligands in a single step. The… read more here.
Keywords: polynuclear complexes; induced regioselective; substituted carboranes; iridium induced ... See more keywords