Mimicking Enzymes: Asymmetric Induction inside a Carbamate-Based Steroidal Cleft.
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DOI: 10.1021/acs.orglett.9b01170
Abstract: Cholic acid has been elaborated into a carbamate-based tripodal architecture, which is able to promote an asymmetric organic transformation inside its chiral cavity. The nature of this steroidal catalyst has been disclosed by quantum-chemical calculations.… read more here.
Keywords: induction inside; enzymes asymmetric; carbamate based; asymmetric induction ... See more keywords