Asymmetric Induction via the Structural Indenyl Effect
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DOI: 10.1021/acs.organomet.7b00841
Abstract: Constrained geometry, planar chiral, dichloro[η5:κS-indenyl-sulfanyl]rhodium complex (pS)-1 reacts with (E)-2-pentene in the presence of silver hexafluoroantimonate to afford syn,syn-1,3-dimethyl-π-allyl complex (pS)-2 in 88% yield. Reaction of (pS)-2 with the sodium or tetrabutylammonium salts of dimethyl… read more here.
Keywords: indenyl effect; via structural; structural indenyl; asymmetric induction ... See more keywords
Cisplatin Induces Senescent Lung Cancer Cell-Mediated Stemness Induction via GRP78/Akt-Dependent Mechanism
Sign Up to like & getrecommendations! Published in 2022 at "Biomedicines"
DOI: 10.3390/biomedicines10112703
Abstract: Cellular senescence is linked with chemotherapy resistance. Based on previous studies, GRP78 is a signal transducer in senescent cells. However, the association between GRP78 and stem cell phenotype remains unknown. Cisplatin treatment was clarified to… read more here.
Keywords: cell; grp78 akt; grp78; stemness induction ... See more keywords