Ultrathin 2D Cerium-Based Metal-Organic Framework Nanosheet That Boosts Selective Oxidation of Inert C(sp3 )H Bond through Multiphoton Excitation.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202300597
Abstract: The development of methodologies for inducing and tailoring activities of catalysts is an important issue in various catalysis. The ultrathin 2D monolayer metal-organic framework (MOF) nanosheets with more accessible active sites and faster diffusion obtained… read more here.
Keywords: organic framework; inert sp3; framework; metal organic ... See more keywords
Vanadium(VIV)-Porphyrin-Based Metal-Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)-H Bonds.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c20420
Abstract: Activation and selective functionalization of inert C(sp3)-H bonds remain one of the most challenging tasks in current synthetic chemistry. Herein, by decorating vanadium(VIV)-porphyrin into metal-organic frameworks (MOFs) to stabilize the active tertbutyl peroxide radical, we… read more here.
Keywords: sp3 bonds; viv porphyrin; inert sp3; activation ... See more keywords