The flexibility of long chain substituents influences spin-crossover in isomorphous lipid bilayer crystals.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc01073e
Abstract: [Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives with a bent geometry of hexadec-1-ynyl or hexadecyl pyrazole substituents are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt, stepwise spin-transition on cooling. This… read more here.
Keywords: chain substituents; long chain; substituents influences; flexibility long ... See more keywords
Influences of spin-orbit coupling on Fermi surfaces and Dirac cones in ferroelectriclike polar metals
Sign Up to like & getrecommendations! Published in 2019 at "Physical Review B"
DOI: 10.1103/physrevb.99.195154
Abstract: Based on first-principles calculations and k .p effective models, we report physical properties of ferroelectric-like hexagonal polar metals with P63mc symmetry, which are distinct from those of conventional metals with spatial inversion symmetry. Spin textures… read more here.
Keywords: dirac cones; coupling fermi; polar metals; influences spin ... See more keywords