Controlled Selectivity through Reversible Inhibition of the Catalyst: Stereodivergent Semihydrogenation of Alkynes
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DOI: 10.1021/jacs.2c04233
Abstract: Catalytic semihydrogenation of internal alkynes using H2 is an attractive atom-economical route to various alkenes, and its stereocontrol has received widespread attention, both in homogeneous and heterogeneous catalyses. Herein, a novel strategy is introduced, whereby… read more here.
Keywords: thiol; catalyst; selectivity; reversible inhibition ... See more keywords