Fluorinated Poly(substituted methylene)s Prepared by Pd-Initiated Polymerization of Fluorine-Containing Alkyl and Phenyl Diazoacetates: Their Unique Solubility and Postpolymerization Modification
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01964
Abstract: Pd-initiated polymerization of fluorine (F)-containing alkyl and phenyl diazoacetates is described. Polymerization of 2,2,2-trifluoroethyl diazoacetate [Et(CF3)DA] with π-allylPdCl afforded a C–C main chain polymer bearing a 2,2,2-trifluoroethoxycarbonyl group on each main chain carbon atom. The… read more here.
Keywords: polymerization; phenyl diazoacetates; initiated polymerization; polymerization fluorine ... See more keywords
Lewis Pair-Mediated Surface-Initiated Polymerization
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.7b00903
Abstract: We present the first example of surface-initiated polymerization mediated by Lewis pairs for the synthesis of polymer brushes on planar substrates. The method enables the rapid grafting polymerization from the self-assembled monolayer or surface-attached macroinitiators,… read more here.
Keywords: polymerization; lewis pair; surface; initiated polymerization ... See more keywords