Preparation of Microporous Organic Polymers via UV-Initiated Radical Copolymerization
Sign Up to like & getrecommendations! Published in 2018 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.8b00688
Abstract: UV-initiated radical copolymerization has been successfully applied for the preparation of two kinds of microporous organic polymers (MOPs) based on divinylbenzene (DVB)/bismaleimide (BMI) monomers... read more here.
Keywords: organic polymers; microporous organic; initiated radical; preparation microporous ... See more keywords
Metal–organic insertion light initiated radical (MILRad) polymerization: photo-initiated radical polymerization of vinyl polar monomers with various palladium diimine catalysts
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c8py01556b
Abstract: The photoinitiated radical polymerization pathway of MILRad polymerization towards its ability to polymerize a variety of vinyl polar functional monomers is investigated. read more here.
Keywords: vinyl polar; milrad polymerization; initiated radical; radical polymerization ... See more keywords
First principle studies on the atmospheric oxidation of HFC-C1436 initiated by the OH radical
Sign Up to like & getrecommendations! Published in 2020 at "New Journal of Chemistry"
DOI: 10.1039/c9nj04908h
Abstract: The atmospheric oxidation mechanism and kinetics of 3,3,4,4,5,5-hexafluorocyclopentene (HFC-C1436) initiated by the OH radical have been investigated using electronic structure calculations. Canonical variation transition state theory was employed to predict the rate constant for the… read more here.
Keywords: hfc c1436; c1436 initiated; initiated radical; atmospheric oxidation ... See more keywords
Oxidative Desymmetrization of Isoindolines Realized by tert-Butyl Nitrite (TBN) Initiated Radical sp3 C–H Activation Relay (CHAR)
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DOI: 10.1055/s-0040-1706010
Abstract: An oxidative desymmetrization of isoindolines was realized by TBN initiated radical sp3 C–H activation relay (CHAR), providing a series of ω-hydroxylactams in high yields. This reaction exhibits broad substrate scope and functional group tolerance, and… read more here.
Keywords: initiated radical; desymmetrization isoindolines; oxidative desymmetrization; desymmetrization ... See more keywords
Visible light–initiated radical 1,3-difunctionalization of β,γ-unsaturated ketones
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DOI: 10.1126/sciadv.abq8596
Abstract: Radical-mediated 1,2-difunctionalization of olefins is a well-established synthetic technique widely used in the rapid construction of structurally diverse molecular entities. However, radical-mediated 1,3-difunctionalization reactions are rare, and the substrates are generally limited to strained skeletons.… read more here.
Keywords: difunctionalization; initiated radical; radical difunctionalization; visible light ... See more keywords