Polymer Brush Growth by Surface‐Initiated Ring‐Opening Polymerization from a Cross‐Linked Polymer Thin Film
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DOI: 10.1002/adfm.202420958
Abstract: Modification of a surface with polymer brushes has emerged as an effective approach to tune the properties of a substrate. Brushes grown from an inimer‐containing cross‐linkable polymer coating provide significant advantages compared to other “grafting‐from”… read more here.
Keywords: surface initiated; polymer; cross; initiated ring ... See more keywords
Adamantyl aziridines via aza-Michael initiated ring closure (aza-MIRC) reaction
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DOI: 10.1016/j.tet.2017.01.006
Abstract: Abstract An efficient one-pot synthesis of functionalized adamantylaziridines by aza-Michael initiated ring closure (aza-MIRC) reaction of 1-aminoadamantane with α-halogenated Michael acceptors is described. The reaction goes through an aza-Michael intermediate that undergoes an intramolecular nucleophilic… read more here.
Keywords: initiated ring; ring closure; aza; reaction ... See more keywords
Hydride transfer initiated ring expansion of pyrrolidines toward highly functionalized tetrahydro-1-benzazepines.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical communications"
DOI: 10.1039/c8cc08238c
Abstract: A novel hydride transfer initiated ring expansion of 4-pyrrolidinyl isatins to synthesize tetrahydro-1-benzazepines has been developed. This methodology represents an atom- and step-economical protocol to assemble seven-membered polycyclic amines from pyrrolidine derivatives in one step. read more here.
Keywords: initiated ring; ring expansion; tetrahydro benzazepines; transfer initiated ... See more keywords