Insertion of CS2 into the Mg-H bond: synthesis and structural characterization of the magnesium dithioformate complex, [TismPriBenz]Mg(κ2-S2CH).
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DOI: 10.1039/c8dt01947a
Abstract: The tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl magnesium hydride compound, [TismPriBenz]MgH, undergoes insertion of CS2 into the Mg-H bond at room temperature to give [TismPriBenz]Mg(κ2-S2CH), the first structurally characterized magnesium dithioformate compound. The dithioformate complex [TismPriBenz]Mg(κ2-S2CH) reacts with (i) CO2… read more here.
Keywords: insertion cs2; tismpribenz s2ch; dithioformate; magnesium ... See more keywords