Insertion of Isonitriles into the M-C Bonds of Group 4 Dialkyl Complexes.
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DOI: 10.1021/jacs.8b05377
Abstract: The 2,3-dimethylbutadiene complexes of Group 4 metals with constrained geometry (cg) ligands have been prepared and found to adopt a supine orientation with σ2,π bonding. Treatment of cgTi(2,3-dimethylbutadiene) (1-Ti) with tBuNC leads to the formation… read more here.
Keywords: isonitriles bonds; insertion; group; insertion isonitriles ... See more keywords
Synthesis of Multisubstituted Guanidines through Palladium-Catalyzed Insertion of Isonitriles
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DOI: 10.1055/s-0037-1610981
Abstract: A new method for the synthesis of multisubstituted guanidines through tandem intermolecular insertion of isonitriles with unactivated amides has been developed. In this study, isonitriles could be used not only as reaction materials but also… read more here.
Keywords: synthesis multisubstituted; multisubstituted guanidines; insertion isonitriles; palladium catalyzed ... See more keywords