Copper-Catalyzed Si-H Bond Insertion Reaction of N-Propargyl Ynamides with Hydrosilanes.
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DOI: 10.1021/acs.orglett.1c03830
Abstract: Transition-metal-catalyzed Si-H bond insertion reactions are generally limited to stabilized diazo compounds. An efficient copper-catalyzed Si-H bond insertion reaction of N-propargyl ynamides with hydrosilanes is described, allowing practical and atom-economic construction of valuable organosilanes in… read more here.
Keywords: bond insertion; catalyzed bond; insertion reaction; bond ... See more keywords