An insight, at the atomic level, into the intramolecular metallophilic interaction in nanoclusters.
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DOI: 10.1039/d2cc00987k
Abstract: The intermolecular metallophilic interaction has been exploited to orderly aggregate nanocluster compounds into multidimensional assemblies, while the intramolecular metallophilic interaction was rarely reported. Herein, based on an Au13Cu2 nanocluster template, the presence of the intracluster… read more here.
Keywords: interaction; insight atomic; level intramolecular; atomic level ... See more keywords
Insight into the atomic-level structure of γ-alumina using a multinuclear NMR crystallographic approach
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DOI: 10.1039/d5sc01198a
Abstract: The combination of multinuclear NMR spectroscopy with 17O isotopic enrichment and DFT calculations provided detailed insight into both the bulk and surface structure of γ-Al2O3. Comparison of experimental 17O NMR spectra to computational predictions confirmed… read more here.
Keywords: spectroscopy; level structure; structure; insight atomic ... See more keywords