Insights into the Activation Mode of α‐Carbonyl Sulfoxonium Ylides in Rhodium‐Catalyzed C−H Activation: A Theoretical Study
Sign Up to like & getrecommendations! Published in 2022 at "ChemistryOpen"
DOI: 10.1002/open.202100254
Abstract: Abstract A computational study has been performed to investigate the mechanism of RhIII‐catalyzed C−H bond activation using sulfoxonium ylides as a carbene precursor. The stepwise and concerted activation modes for sulfoxonium ylides were investigated. Detailed… read more here.
Keywords: activation; insights activation; sulfoxonium ylides; activation mode ... See more keywords
Mechanistic Insights into Activation of Carbon Monoxide, Carbon Dioxide, and Nitrous Oxide by Acyclic Silylene.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00903
Abstract: Owing to an empty p orbital and a lone pair of electrons on the Si center, silylene exhibits reactivity similar to a transition-metal system capable of activating H2/C-H bonds and small molecules. In this work,… read more here.
Keywords: activation carbon; carbon; acyclic silylene; insights activation ... See more keywords
Insights on the Activation and Stabilization of NCA Cathode Interface: Surface Chemical State Modulations of Aluminum-Mediated Li0.73CoO2 Coatings
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c05229
Abstract: Layered nickel-rich cathodes generally suffer from their unstable surface because of lithium impurities. Thus, building an interface with both high electrochemical stability and electroactivity is ... read more here.
Keywords: activation stabilization; stabilization nca; surface; interface ... See more keywords