Mechanistic insights into asymmetric reductive coupling of isoquinolines by a chiral diboron with DFT calculations
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DOI: 10.1016/j.jorganchem.2018.02.001
Abstract: Abstract We report our complete mechanistic study on the highly diastereo- and enantioselective reductive coupling of isoquinoline templated by a chiral diboron. An uncommon activation mode, activation of the B-B bond via double N-B coordination… read more here.
Keywords: diboron; insights asymmetric; chiral diboron; reductive coupling ... See more keywords