Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis{1,2,3-triazolylidene}pyridine pincer complexes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.01.003
Abstract: Transmetallation of newly designed lutidine-based CNC or CNN ligands L, featuring flanking 1,2,3-triazolylidene (tzNHCs) moieties, from Ag(I) to Ru(II) provided access to well-defined cationic [RuII(CO)(H)(L)(PPh3)]+ complexes 2 and 5. Spectroscopic investigations confirm that, in both… read more here.
Keywords: ester hydrogenation; ester; mechanistic insights; catalytic carboxylic ... See more keywords
Novel Insights into the Catalytic Mechanism of Collagenolysis by Zn(II)-Dependent Matrix Metalloproteinase-1
Sign Up to like & getrecommendations! Published in 2024 at "Biochemistry"
DOI: 10.1021/acs.biochem.4c00076
Abstract: Collagen hydrolysis, catalyzed by Zn(II)-dependent matrix metalloproteinases (MMPs), is a critical physiological process. Despite previous computational investigations into the catalytic mechanisms of MMP-mediated collagenolysis, a significant knowledge gap in understanding remains regarding the influence of… read more here.
Keywords: dependent matrix; collagenolysis; insights catalytic; mechanism ... See more keywords
Insights into the Catalytic Mechanism of Domains CD1 and CD2 in Histone Deacetylase 6 from Quantum Calculations
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c04729
Abstract: The histone deacetylase 6 enzyme, HDAC6, is a metalloprotein with multiple pathophysiological roles and, as such, is the subject of intense research and drug discovery efforts. Different from the H... read more here.
Keywords: insights catalytic; histone deacetylase; mechanism domains; histone ... See more keywords
Structural insights into the catalytic selectivity of glycosyltransferase SgUGT94-289-3 towards mogrosides
Sign Up to like & getrecommendations! Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-50662-w
Abstract: Mogrosides constitute a series of natural sweeteners extracted from Siraitia grosvenorii fruits. These mogrosides are glucosylated to different degrees, with mogroside V (M5) and siamenoside I (SIA) being two mogrosides with high intensities of sweetness.… read more here.
Keywords: sgugt94 289; catalytic selectivity; glycosyltransferase sgugt94; glycosyltransferase ... See more keywords
Theoretical Insights into the Catalytic Mechanisms of LiNi1/3Co1/3Mn1/3O2 Cathode Surface in Diverse Ethylene Carbonate Decomposition Reactions
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Materials Chemistry A"
DOI: 10.1039/d5ta03903g
Abstract: The surface structural degradation of the cathode commonly results from the decomposition of electrolytes at the cathode material surfaces of lithium-ion batteries, which are closely related to the cathode electrolyte... read more here.
Keywords: theoretical insights; insights catalytic; cathode; surface ... See more keywords