Mechanistic insights into catalytic carboxylic ester hydrogenation with cooperative Ru(II)-bis{1,2,3-triazolylidene}pyridine pincer complexes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.01.003
Abstract: Transmetallation of newly designed lutidine-based CNC or CNN ligands L, featuring flanking 1,2,3-triazolylidene (tzNHCs) moieties, from Ag(I) to Ru(II) provided access to well-defined cationic [RuII(CO)(H)(L)(PPh3)]+ complexes 2 and 5. Spectroscopic investigations confirm that, in both… read more here.
Keywords: ester hydrogenation; ester; mechanistic insights; catalytic carboxylic ... See more keywords
Insights into the Catalytic Mechanism of Domains CD1 and CD2 in Histone Deacetylase 6 from Quantum Calculations
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c04729
Abstract: The histone deacetylase 6 enzyme, HDAC6, is a metalloprotein with multiple pathophysiological roles and, as such, is the subject of intense research and drug discovery efforts. Different from the H... read more here.
Keywords: insights catalytic; histone deacetylase; mechanism domains; histone ... See more keywords